Tuesday, May 12, 2009

Water

The Chemistry of Water and the environment

By Andrew Glory Mtewa

 

Water is one commodity, usually taken for granted, whose value people realize when it becomes scarce. In its abundance, nobody dares to look after and care for it.

Water is the basic necessity for life of animals and plants.

It is essential for chemical dissolutions, transportation and sometimes cooling. Water becomes scarce due to drought, and pollution among other factors. An environment is conducive to life if it has un polluted water.

In this article, I will concentrate on how adverse it is to life to neglect pollution of water in our environment with a few suggestions that can help us manage pollution of water in our local setting. I will briefly tackle both water and effects of careless waste dumping in our environments including agricultural chemicals management.

 

It is widely known that water has two basic components which are hydrogen atoms and an oxygen molecule (H2O). However, there are ideally some other elements that are found in the water that we use from time to time. Water may also contain metals and salts, acids and bases.

If we do not take care of the water bodies that we have, the water becomes po0lluted.

 

Sources of water pollution

 

Presence of agents of water-borne infectious diseases and toxic chemical components in water are major threats of water pollution. The microbes when multiplied cause major epidemics like cholera and typhoid fever. These are common in areas close to rivers, swamps and dams. Water bodies In areas close to plants that use or produce chlorides, i.e. sewage, life in water is affected by some chloride salts like trihalomethanes which is a hazardous chemical. Other chemicals are as follows:

Lead (Pb)

Lead is very common in household water. As time goes, lead gets eroded from the pipes, if they were made with some lead, through a process called plumbosolvency. This is due to force from constant fast running water within some range of pH and temperature variations. Too much lead affects the neuro-physiology of animals resulting to disordered behaviour.

Nitrates (NO3-)

Nitrates tend to pollute our water systems particularly from the use of nitrogenous fertilizers and a bit from the changes from pasture land to arable lands in low lying lands close to water bodies. Too much nitrates from water into the blood systems reduce oxygen carrying capacity. Formation of N-nitroso compounds, a toxic compound from nitrogen may be carcinogenic to animals.

Pesticides

These are essential as they are used to control living organisms in agricultural outputs. However, if they are improperly handled, they may be exposed either deliberately or by accident. In rainy seasons, when farmers are busy applying various pesticides in their fields, some of the remains of the pesticide chemicals are washed away to low lands and eventually pollute water in bore holes, as a case of rural areas and rivers.

 

The sad thing in polluting water bodies is that a large population of aquatic organisms, most of which are edible are contaminated by poisons. If it is an example of fish, the same will be taken to the market where you and I will buy for a meal at home. The poisonous chemical remains, though at low concentration accumulates little by little in our bodies until a time when they are become toxic enough to influence a bad health in our bodies. The impact may be observed over a long period.

 

Control and management of  pollutants

It is a responsible of every citizen to ensure safety of water ion our environment. Watersheds are one of the most vulnerable areas to pollution. These areas need to be protected at all cost with the reinforcement of by-laws and several pieces of legislation if possible. Locally, chiefs and village headmen need to organize several civic education campaigns towards pollution control and management and best chemical use.

 

Regulators, distributors and all stake holders in pesticides and agricultural chemicals should be cooperative enough with each other to ensure effective measures are being implemented. Registration of any new pesticides with the Pesticide control boards enables checks of admissible concentrations of the elements in the chemicals.

Some farmers who are used to buy chemicals in bulks eventually find themselves remaining with chemicals banned for use in the fields. They see it as a loss to discard these items and eventually, they still use the chemicals in their fields. This is one other area that needs to be checked. Extension workers can facilitate this work well as they are familiar with the type of people they are dealing with.

 

There is need to control use of some chemicals and to protect all vulnerable zones.

Chemically, though expensive, use of ion exchange resins can help to get rid of some salts that are harmful in water. Conversion of nitrogen salts to gas or bio nitrification is another way to use whilst getting advantage of living microbes life cycles.

Developing countries like Malawi can benefit a lot from abiding to agreements that were made at international levels on pollution management.

 

One of these is the Dubai convention that among other things ensures the role of the state in creating a healthy and well sustainable environment. Through such ways, countries will be able to achieve sound management of chemicals throughout their life cycle, minimizing significant adverse effects on the environment at large.

However, developing countries like ours essentially lack this capacity to ensure that everybody at every part of the country is following measures to manage pollution.

 

One other thing worth noting is the use of un labelled, expired and banned chemicals. It should be made sure by all stake holders that have knowledge of the chemicals they are using at a particular time. Some chemicals are sold at black markets with no details of their toxicity, concentration and properties. This can not spearhead the campaign towards a safe environment. These chemicals on the black market are usually cheap and many people flock to them.

 

Another point of concern to the health of our environment is damping. I appreciate that lack of proper structures for dumping in our townships is prevalent. In areas like kawale, Biwi, area 25, Bangwe and other river bank areas seem to have a great deal of problems hoe to manage wastes. It is very sad that some damping areas for the entire community are close to primary schools. Being well mindful that some wastes are toxic, it is a hazard to life to have landfills and dumping areas situated very close to schools and residential areas. I have used the term landfill in this case because the dumping areas are usually neglected for a very long time without being collected by the assembly until one time, a friend from mzuzu approached me that they had a similar problem and wanted to sue the assembly for risking their lives. Many persistent chemical derivatives from expired medicine, lotions, petroleum cans, ethylene and body wastes are all in the landfill heaps that we see.

 Disease causing pathogens are breeding themselves right there. it is terminating our own species if we are not to take care of our own environment.

Problems of this type are worse during rain seasons. It is best to make a team initiative in our communities to manage our environment. Let us learn to manage our water, and this will save us, save our animals and save our plants. The ecosystem will be flowing in a smooth chain of a healthy life. It all almost starts with water……..clean water, safe water, safe livelihood. Love your life, conserve your environment.

 

 

Acknowledgements

Report of the united Nations conference on Environmental and development, Rio de Janeiro, 3-14 June, 1992. United nations Publications

Report of the World summit on sustainable development, Johannesburg, south Africa. 26th august-4th September,2002. united Nations publications

Strategic approach to international chemicals management, 6th June, 2006. secretariat for the strategic approach to international Chemicals management

 

 

 

 

 

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More from Dr. Anne marie Helmenstine

Make Biodiesel - Instructions for Making Biodiesel from Vegetable Oil



Save Money Making Your Own Biodiesel
By Anne Marie Helmenstine, Ph.D., About.com

It's easy and cost-effective to make your own biodiesel.
Biodiesel Engine Biodiesel Plant How to Make Biodiesel Biodiesel Production Making Biodiesel

Biodiesel is a diesel fuel that is made by reacting vegetable oil (cooking oil) with other common chemicals. Biodiesel may be used in any diesel automotive engine in its pure form or blended with petroleum-based diesel. No modifications are required, and the result is a less-expensive, renewable, clean-burning fuel. Here's how to make biodiesel from fresh oil. You can also make biodiesel from waste cooking oil, but that is a little more involved, so let's start with the basics.

Materials for Making Biodiesel

· 1 liter of new vegetable oil (e.g, canola oil, corn oil, soybean oil)
· 3.5 grams (0.12 oz.) sodium hydroxide (also known as lye). Sodium hydroxide is used for some drain cleaners, such as Red Devil™ drain cleaner. The label should state that the product contains sodium hydroxide (not calcium hypochlorite, which is found in many other drain cleaners)

· 200 milliliters (6.8 fl. oz.) of methanol (methyl alcohol). Heet™ fuel treatment is methanol. Be sure the label says the product contains methanol (Isoheet™, for example, contains isopropyl alcohol and won't work).

· blender with a low speed option. The pitcher for the blender is to be used only for making biodiesel. You want to use one made from glass, not plastic, since the methanol you will use can react with plastic.

· digital scale [to accurately measure 3.5 grams (0.12 oz.)]

· glass container marked for 200 milliliters (6.8 fl. oz.). If you don't have a beaker, measure the volume using a measuring cup, pour it into a glass jar, then mark the fill-line on the outside of the jar.

· glass or plastic container that is marked for 1 liter (1.1 quart)

· wide mouth glass or plastic container that will hold at least 1.5 liters (2-quart pitcher works well)

· safety glasses, gloves, and probably an apron. You do not want to get sodium hydroxide or methanol on your skin, nor do you want to breathe the vapors from either chemical. Both chemicals are toxic. Please read the warning labels on the containers for these products! Methanol is readily absorbed through your skin, so do not get it on your hands. Sodium hydroxide is caustic and will give you a chemical burn. Prepare your biodiesel in a well-ventilated area. If you spill either chemical on your skin, rinse it off immediately with water.

Let's Make Biodiesel!

1. You want to prepare the biodiesel in a room-temperature (70° F) or warmer room since the chemical reaction will not proceed to completion if the temperature is too low.

2. If you haven't already, label all your containers as 'Toxic - Only Use for Making Biodiesel', since you don't want anyone drinking your supplies and you don't want to use the glassware for food again.

3. Pour 200 ml methanol (Heet) into the glass blender pitcher.

4. Turn the blender on its lowest setting and slowly add 3.5 g sodium hydroxide (lye). This reaction produces sodium methoxide, which must be used right away or else it loses its effectiveness. (Like sodium hydroxide, it can be stored away from air/moisture, but that might not be practical for a home setup.)

5. Mix the methanol and sodium hydroxide until the sodium hydroxide has completely dissolved (about 2 minutes), then add 1 liter of vegetable oil to this mixture.

6. Continue blending this mixture (on low speed) for 20-30 minutes.

7. Pour the mixture into a wide-mouth jar. You will see the liquid start to separate out into layers. The bottom layer will be glycerin. The top layer is the biodiesel.

8. Allow at least a couple of hours for the mixture to fully separate. You want to keep the top layer as your biodiesel fuel. If you like, you can keep the glycerin for other projects. You can either carefully pour off the biodiesel or use a pump or baster to pull the biodiesel off of the glycerin.

Using Biodiesel

Normally you can use pure biodiesel or a mixture of biodiesel and petroleum diesel as a fuel in any unmodified diesel engine. There are two situations in which you definitely should mix biodiesel with petroleum-based diesel.

· If you are going to be running the engine at a temperature lower than 55° F (13° C), you should mix biodiesel with petroleum diesel. A 50:50 mixture will work for cold weather. Pure biodiesel will thicken and cloud at 55° F, which could clog your fuel line and stop your engine. Pure petroleum diesel, in contrast, has a cloud point of -10° F (-24° C). The colder your conditions, the higher percentage of petroleum diesel you will want to use. Above 55° F you can use pure biodiesel without any problem. Both types of diesel return to normal as soon as the temperature warms above their cloud point.

· You will want to use a mixture of 20% biodiesel with 80% petroleum diesel (called B20) if your engine has natural rubber seals or hoses. Pure biodiesel can degrade natural rubber, though B20 tends not to cause problems. If you have an older engine (which is where natural rubber parts are found), you could replace the rubber with polymer parts and run pure biodiesel.

Biodiesel Stability & Shelf Life

You probably don't stop to think about it, but all fuels have a shelf life that depends on their chemical composition and storage conditions. The chemical stability of biodiesel depends on the oil from which it was derived. Biodiesel from oils that naturally contain the antioxidant tocopherol or vitamin E (e.g., rapeseed oil) remain usable longer than biodiesel from other types of vegetable oils. According to at least one source stability is noticeably diminished after 10 days and the fuel may be unusable after 2 months. Temperature also affects fuel stability in that excessive temperatures may denature the fuel.

What Is the Difference Between a Scientist and an Engineer?


By Anne Marie Helmenstine, Ph.D., About.com

Chemical engineers supervise the central pumping station at the Yukos Oil and Gas company in Nefteyugansk, Siberia.

Links

Chemical Software FreeMolecular Builder and Property Estimation Neural Networkwww.bestsystems.co.jp
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Question: What Is the Difference Between a Scientist and an Engineer?

Scientist versus engineer... are they the same? Different? Here's a look at the definitions of scientist and engineer and the difference between a scientist and engineer.

Answer: A scientist is a person who has scientific training or who works in the sciences. An engineer is someone who is trained as an engineer. So, to my way of thinking, the practical difference lies in the educational degree and the description of the task being performed by the scientist or engineer. On a more philosophical level, scientists tend to explore the natural world and discover new knowledge about the universe and how it works.

Engineers apply that knowledge to solve practical problems, often with an eye toward optimizing cost, efficiency, or some other parameters.

There is considerable overlap between science and engineering, so you will find scientists who design and construct equipment and engineers who make important scientific discoveries. Information theory was founded by Claude Shannon, a theoretical engineer. Peter Debye won the Nobel Prize in Chemistry with a degree in electrical engineering and a doctorate in physics.

Do you feel there are important distinctions between scientists and engineers? You're invited to define the difference.

Why is Stainless Steel Stainless?


What It Is and How It Works!

By Anne Marie Helmenstine, Ph.D., About.com

What Is Stainless Steel and Why Is it Stainless?

In 1913, English metallurgist Harry Brearly, working on a project to improve rifle barrels, accidentally discovered that adding chromium to low carbon steel gives it stain resistance.

In addition to iron, carbon, and chromium, modern stainless steel may also contain other elements, such as nickel, niobium, molybdenum, and titanium. Nickel, molybdenum, niobium, and chromium enhance the corrosion resistance of stainless steel. It is the addition of a minimum of 12% chromium to the steel that makes it resist rust, or stain 'less' than other types of steel.

The chromium in the steel combines with oxygen in the atmosphere to form a thin, invisible layer of chrome-containing oxide, called the passive film. The sizes of chromium atoms and their oxides are similar, so they pack neatly together on the surface of the metal, forming a stable layer only a few atoms thick. If the metal is cut or scratched and the passive film is disrupted, more oxide will quickly form and recover the exposed surface, protecting it from oxidative corrosion. (Iron, on the other hand, rusts quickly because atomic iron is much smaller than its oxide, so the oxide forms a loose rather than tightly-packed layer and flakes away.)

The passive film requires oxygen to self-repair, so stainless steels have poor corrosion resistance in low-oxygen and poor circulation environments. In seawater, chlorides from the salt will attack and destroy the passive film more quickly than it can be repaired in a low oxygen environment.

Types of Stainless Steel

The three main types of stainless steels are austenitic, ferritic, and martensitic. These three types of steels are identified by their microstructure or predominant crystal phase.

Austenitic: Austenitic steels have austenite as their primary phase (face centered cubic crystal). These are alloys containing chromium and nickel (sometimes manganese and nitrogen), structured around the Type 302 composition of iron, 18% chromium, and 8% nickel. Austenitic steels are not hardenable by heat treatment.

The most familiar stainless steel is probably Type 304, sometimes called T304 or simply 304. Type 304 surgical stainless steel is an austenitic steel containing 18-20% chromium and 8-10% nickel.

Ferritic: Ferritic steels have ferrite (body centered cubic crystal) as their main phase. These steels contain iron and chromium, based on the Type 430 composition of 17% chromium. Ferritic steel is less ductile than austenitic steel and is not hardenable by heat treatment.

Martensitic: The characteristic orthorhombic martensite microstructure was first observed by German microscopist Adolf Martens around 1890. Martensitic steels are low carbon steels built around the Type 410 composition of iron, 12% chromium, and 0.12% carbon. They may be tempered and hardened. Martensite gives steel great hardness, but it also reduces its toughness and makes it brittle, so few steels are fully hardened.

There are also other grades of stainless steels, such as precipitation-hardened, duplex, and cast stainless steels. Stainless steel can be produced in a variety of finishes and textures and can be tinted over a broad spectrum of colors.

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